AlpHa Measurement Solutions |
Ion-Selective Electrodes in Power Generation
ISE in Power Generation
Ion-selective electrodes (ISE) are utilized in various power generation applications. Measuring specific ion concentrations can be an important indicator for purity, performance, and efficiency:
- Sodium in boiler feedwater and steam to indicate purity/contamination
- Chloride to ensure purity of boiler cleaning solutions, boiler feedwater, and other high purity waters / effluents
- Fluoride in nuclear fuel reprocessing
- Water hardness, also referred to as total calcium and magnesium, to confirm performance of membrane filtration, reverse osmosis (RO) systems, and ion-exchange systems
Traditional off-site measurements may introduce potential contamination, time loss, and operating errors during sample transfers. These disadvantages can be eliminated through on-site ISE measurements. AlpHa offers various mechanical insertion assemblies, specialized housing materials, and reference systems for the required specifications. AlpHa’s ISE portfolio can target over twenty different ions which are designed for both lab and continuous process environments.
| Ion-Selective Electrode | Range @ 25°C | Technology Type | Temp. Range | Warranty |
| Ammonia (NH3) | 0.01 – 17,000 ppm as NH3 | Gas Sensing | 0 – 50°C | 12 Months |
| Ammonium (NH4+) | 0.1 – 14,000 ppm as N | PVC Membrane | 0 – 40°C | 6 Months |
| Bromide (Br-) | 0.2 – 79,900 ppm | Solid State Pellet | 0 – 80°C | 12 Months |
| Cadmium (Cd2+) | 0.01 – 11,200 ppm | Solid State Pellet | 0 – 80°C | 12 Months |
| Calcium (Ca2+) | 0.5 – 40,100 ppm | PVC Membrane | 0 – 40°C | 6 Months |
| Carbon Dioxide (CO2) | 4.4 – 440 ppm | Gas Sensing | 0 – 50°C | 12 Months |
| Chloride (Cl-) | 1.8 – 35,000 ppm | Solid State Pellet | 0 – 80°C | 12 Months |
| Copper (Cu2+) | 0.064 – 6,400 ppm | Solid State Pellet | 0 – 80°C | 12 Months |
| Cyanide (CN-) | 0.2 – 260 ppm | Solid State Pellet | 0 – 80°C | 12 Months |
| Fluoride (F-) | 0.02 – 19,000 ppm | Solid State Crystal | 0 – 80°C | 12 Months |
| Fluoroborate (BF4-) | Varies | PVC Membrane | 0 – 40°C | 6 Months |
| Iodide (I-) | 0.01 – 127,000 ppm | Solid State Pellet | 0 – 80°C | 12 Months |
| Lead (Pb2+) | 0.2 – 20,700 ppm | Solid State Pellet | 0 – 80°C | 12 Months |
| Lithium (Li+) | 0.2 – 10,000 ppm | PVC Membrane | 0 – 40°C | 6 Months |
| Magnesium (Mg2+) | 0.1 – 30,000 ppm | PVC Membrane | 0 – 40°C | 6 Months |
| Nitrate (NO3-) | 0.1 – 14,000 ppm as N | PVC Membrane | 0 – 40°C | 6 Months |
| Nitrogen Oxide (NOx) | Varies | Gas Sensing | 0 – 50°C | 12 Months |
| Perchlorate (ClO4-) | Varies | PVC Membrane | 0 – 40°C | 6 Months |
| Potassium (K+) | 0.04 – 39,000 ppm | PVC Membrane | 0 – 40°C | 6 Months |
| Silver (Ag+) | 0.01 – 107,900 ppm | Solid State Pellet | 0 – 80°C | 12 Months |
| Sulfide (S2-) | 0.01 – 32,100 ppm | Solid State Pellet | 0 – 80°C | 12 Months |
| Sodium (Na+) | 0.01 – 100,000 ppm | Sensing Glass | 0 – 80°C | 12 Months |
| Surfactant (X+ / X-) | Varies | PVC Membrane | 0 – 40°C | 6 Months |
| Water Hardness (Ca2+ / Mg2+) | 0.5 – 40,000 ppm | PVC Membrane | 0 – 40°C | 6 Months |
- Form Factor
- 12 mm
- Process Body
- Cartridge
- Custom Options Available
- Housing Material Options
- Glass
- Ryton® (PPS)
- ABS
- Epoxy
- Polycarbonate
- Kynar® (PVDF)
- Polyethylene
- PEEK
- PVC / CPVC
- Teflon™ (PTFE)
- Ultem® (PEI)
- Custom Options Available
- Thermistor Options
- Not commonly integrated, however, optional per design requirements
- Reference System
- Ag / AgCl
- Custom Options Available
- Reference Junction Options
- Single Junction
- Double Junction
- Custom Options Available
- Reference Junction Material / Design
- Ceramic Pin / Annular / Disc
- Fiber / Pellon
- Open Aperture
- Porous Plastic (PTFE / HDPE / PP)
- Sleeve Junction / Free Flow (liquid / liquid or ground glass joint)
- Solid State
- Custom Options Available
- Reference Electrolyte
- Sealed
- Soft Gel
- Solid Gel
- Refillable
- Liquid
- Soft Gel
- Custom Options Available
- Sealed
- Integrated Insertions
- PG 13.5
- 3/4" NPT
- 1/2" NPT
- 1" NPT
- Custom Options Available
- Analog
- Millivolts
- 0 – 5 V
- 0 – 10 V
- 4 – 20 mA
- Custom Options Available
- Digital
- RS-485 MODBUS RTU
- Custom Options Available
- Connectors
- Integrated Connectors (detachable or cableless)
- S7
- S8
- Integrated BNC
- Variopin
- Custom Options Available
- Connectors with Cables (including temperature)
- BNC
- DIN
- MOLEX
- Tinned Leads
- Mil-spec
- 2.5 mm / 3.5 mm phono
- RCA
- Spade Lugs
- LEMO
- Circular Connectors
- Any commercially available connectors and custom options available
- Integrated Connectors (detachable or cableless)